Quantum Effects in Chemical Reactions under Polaritonic Vibrational Strong Coupling

Quantum effects in electron transfer reactions with strong electronic coupling

Quantum Indistinguishability in Chemical Reactions

Quantum indistinguishability plays a crucial role in many low-energy physical phenomena, from quantum fluids to molecular spectroscopy. It is, however, typically ignored in most high temperature processes, particularly for ionic coordinates, implicitly assumed to be distinguishable, incoherent and thus well-approximated classically. We explore chemical reactions involving small symmetric molecu...

Quantum solitons at strong coupling

We examine the effect of one loop quantum corrections on the formation of nontopological solitons in a strongly coupled scalar-fermionic Yukawa theory. The exact one fermion loop contribution is incorporated by using a nonlocal method to correct the local derivative expansion approximation (DE) of the effective action. As the Yukawa coupling is increased we find that the nonlocal corrections pl...

Signatures of Vibrational Strong Coupling in Raman Scattering

We have analyzed theoretically how the emergence of collective strong coupling between vibrational excitations and confined cavity modes affects Raman scattering processes. This work was motivated by recent experiments (Shalabney et al. Angew. Chem., Int. Ed. 2015, 54, 7971) that reported enhancements of up to 3 orders of magnitude in the Raman signal. By using different models within linear re...

Strong Coupling Perturbation Theory in Quantum Mechanics

We present a full introduction to the recent devised perturbation theory for strong coupling in quantum mechanics. In order to put the theory in a proper historical perspective, the approach devised in quantum field theory is rapidly presented, showing how it implies a kind of duality in perturbation theory, from the start. The approach of renormalization group in perturbation theory is then pr...